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The interaction of formic acid with TiO 2 thin films and rutile TiO 2 (110) has been compared using high-resolution electron energy-loss spectroscopy (HREELS). Between 260 and 300K the spectra are consistent with surface formate bonded to titanium sites, a consequence of dissociative chemisorption. For a four-layer TiO 2 (110) film, the 220cm -1 separation of ν...
The effect of coadsorbed Pd on the adsorption of HCOOH on TiO 2 (110) at room temperature has been investigated using HREELS. At Pd coverages below 12ML, formate is evidenced that is probably bonded to Ti sites on bare areas of the substrate. Additional C O species are identified corresponding to CO bound to Pd clusters as well as HCO and/or CO bound to sites at the perimeter of the clusters...
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