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Oxidation of quaternary ammonium substrate, carnitine by non‐heme iron containing Acinetobacter baumannii (Ab) oxygenase CntA/reductase CntB is implicated in the onset of human cardiovascular disease. Herein, we develop a blue‐light (365 nm) activation of NADH coupled to electron paramagnetic resonance (EPR) measurements to study electron transfer from the excited state of NADH to the oxidized, Rieske‐type,...
Eines ist nicht wie die anderen: Die Titelsynthese umfasst die stufenweise Kupplung dreier relativ einfacher Substrate. Drei Reagentien werden beschrieben, eines davon mit einer naturstoffartigen Toxizität für HeLa‐ und MCF7‐Zellen. Es ist isoformselektiv und greift Hsp90α/β bevorzugt vor Grp94 an. Seine Konformation im Komplex mit Hsp90 ähnelt der von Geldanamycin.
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