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The crystal structure of magnesium potassium arsenate hexahydrate, MgKAsO4·6H2O, was refined from powder diffraction data. MgKAsO4·6H2O crystallizes in the orthorhombic space group Pmn21 with Z = 2, as the biomineral struvite. Complete dehydration of MgKAsO4·6H2O proceeds in a single step, with one endothermic peak at 87.9 °C (Tonset). The infrared and Raman spectra of protiated and deuterated polycrystalline...
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