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Fluoromethylating agents are a highly studied and controversely discussed class of compounds. New fluoromethyl pseudohalides FCH2N3, FCH2SCN, and FCH2SeCN were prepared for the first time and their physical and spectroscopic properties investigated. Their synthesis is performed conveniently by fluoromethylation of the respective silver or potassium pseudohalogenides with fluoroiodomethane.
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