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The stannide LaPdSn has been synthesized by arc-melting and the structure has been refined from X-ray single crystal diffractometer data: TiNiSi type, Pnma, a = 763.8(1), b = 473.47(7), c = 799.4(1) pm, wR2 = 0.0417, 548 F 2 values, 20 variables. The electronic structures of LaPdSn, La 3 Pd 4 Sn 6 and Ce 3 Pd 4 Sn 6 (own type) were investigated...
The plumbide CeZnPb was synthesized from the elements in a sealed tantalum ampoule. Its YPtAs-type structure was refined on the basis of single-crystal X-ray diffraction data: P6 3 /mmc, a = 463.7(2) and c = 1669.6(6) pm, wR2 = 0.1161, 189 F 2 values, and 12 variables. CeZnPb crystallizes with a superstructure of AlB 2 . The zinc and lead atoms form puckered [Zn 3 Pb...
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