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Hydrothermal reactions of benzimidazole-5-carboxylate acid (HL) and cadmium(II) nitrate under base conditions lead to a novel three-dimensional microporous coordination polymer [Cd(L) 2 ]·H 2 O (1). Topologically, it can be described as an eight-connected CsCl-type net (4 24 6 4 ) utilizing bicadmium cores as eight-connected nodes and HL as linkers. A blue fluorescence...
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