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The spin exchange interactions of VO(CH 3 CO 2 ) 2 and VO(OCH 2 CH 2 O) were investigated by performing spin dimer analysis based on tight binding calculations and mapping analysis based on first principles density functional theory calculations. In agreement with experiment, both analyses show that the magnetic properties of VO(CH 3 CO 2 ) ...
Spin dimer analysis was carried out for the magnetic oxides of V 4+ (d 1 ) ions, A 2 V 3 O 9 (A=Ba, Sr) and η-Na 9 V 14 O 35 , to account for their magnetic structures. After identifying the V(O eq ) 4 square planes containing the magnetic orbitals of the V 4+ (d 1 ) ions, we analyzed the relative strengths...
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