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Large band gap and strong nonlinear optical (NLO) effect are two valuable but contradictory parameters, which are difficult to balance in one infrared (IR) NLO material. Herein, the first alkali and alkaline‐earth metal diamond‐like (DL) IR NLO material Li4MgGe2S7, presenting a honeycomb‐like 3D framework constructed by 6‐membered LiS4 rings and GeMgS6 zigzag chains, was rationally designed and synthesized...
Alkali‐ und Erdalkalimetalltetraeder in Kombination mit einem diamantähnlichen Strukturtemplat (DLS) lieferten das erste nichtlinear‐optische (NLO) Material Li4MgGe2S7 mit Alkali‐ und Erdalkalimetallen. Diese Arbeit erweitert die Vielfalt der DLS‐Verbindungen und eröffnet einen Weg für die Entwicklung und Erforschung neuer Infrarot‐NLO‐Materialien mit hervorragenden NLO‐Eigenschaften, wie Shilie Pan,...
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