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Bi4Ti3O12 high‐temperature piezoelectric ceramics composed of 0.03 mol (Nb, Ta)5+ substituting B site and x mol CeO2 (x = 0–0.05, abbreviated as BCTNT100x) substituting A site were synthesized by the conventional solid‐state reaction method. The effects of Ce additive on the structures and electrical properties of resulting Bi4Ti3O12‐based ceramics were systematically investigated. In‐situ temperature‐dependent...