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Two new coordination polymers (CPs), [InCl(H2bidc)2(H2O)]n (1) and [Sc(Hbidc)(OH)(H2O)]n (2) (H3bidc = benzimidazole-5,6-dicarboxylic acid) were synthesized through a solvothermal approach. 1 exhibits a 1D infinite chain, which further constructs a 3D supramolecular framework via hydrogen bonds. 2 features a 3D supramolecular framework consisting of left- and right-handed chiral layers, which contain...
A family of octanuclear clusters [FeIII4LnIII4O2(OH)4(mosaoH)4 (Piv)4(N-mdea)4(H2O)2] [Ln=Y(1), Gd(2), Tb(3) and Dy(4), mosaoH2=3-Methyloxysalicylaldoxime, N-mdeaH2=N-methyl diethanolamine, pivH=pivalic acid] has been prepared by reactions of [Fe3O(piv)6(OH2)2(OH)]·H2O with Ln(NO3)3·6H2O, mosaoH2 and N-mdeaH2 ligands. The crystal structures of 1–4 were obtained, and their core can be described as...
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