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A planar energetic molecule with high density, 5,5′‐dinitramino‐3,3′‐azo‐1,2,4‐oxadiazole (4), was obtained by the nitration of 5,5′‐diamino‐3,3′‐azo‐1,2,4‐oxadiazole using 100 % nitric acid. In addition, selected nitrogen‐rich salts were prepared. Of them, the neutral compound 4 and its hydroxylammonium salt, 6, were further confirmed by single‐crystal X‐ray diffraction. Physicochemical and energetic...
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