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In‐situ UV–Vis spectroscopy was used for investigating the evolution of silver nanoparticles (NPs) inside the gas aggregation cluster source (GAS). The light beam probed the interior of the GAS at different distances from the magnetron. Plasmon resonance was detected at 365 nm, with the highest intensity found close to the magnetron due to the NP trapping. Time‐resolved measurements revealed that...
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