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Fabrication of Bi-free transparent TiO 2 glass-ceramics was attained by substitution a mixture of alkaline earth oxide and ZnO for Bi 2 O 3 . It is suggested that ZnO, which can play a role of both intermediate and network modifier, is important for the substitution. Observed particle size of precipitated anatase in the glass-ceramics was several nanometers enough to possess...
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