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Black wattle tannin‐immobilized mesostructured collagen (TC) was synthesized by using exfoliated mesostructured collagen as carriers. The structure of TC was characterized by scanning electron microscope, Fourier transform infrared spectroscopy and zeta potential test. Methylene blue (MB) as a cationic dye model was applied to evaluate the adsorption ability of TC through batch and continuous fixed‐bed...