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This chapter begins by describing the synthesis and structure of α‐zirconium phosphate (α‐ZrP), Zr(O3POH)2·H2O. Selectivities of cations with higher charge are preferred by the amorphous (gel) ZrP, and some interesting separations of radioisotopes have been carried out using chromatographic separations. The amorphous zirconium phosphate was found to be active in the separation of radioactive ions...
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