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Telechelic poly(n-butyl acrylate) and poly[poly(ethylene glycol) methyl ether acrylate] are obtained with high monomer conversions and narrow molecular weight distributions (Ð<1.2) by Cu(0)-mediated living radical polymerization (SET-LRP). The high end group fidelity of the polymer is confirmed by a combination of 1H NMR and MALDI-ToF-MS analysis. The reactivity of the telechelics is exploited...
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