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Triethoxysilyl‐terminated poly(d‐lactide)s (eSi‐PDLA) were successfully prepared by hydrosilylation of allyl‐terminated PDLAs (A‐PDLA‐ac) which were readily prepared by ring‐opening polymerization of d‐lactide and the following terminal protection by acetylation. Their acid‐catalyzed hydrolysis produced hyper‐conjugated PDLAs with terminal silanol coupling. Blend PLLA films containing eSi‐PDLA (Mn...
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