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Bacterial poly(3-hydroxybutyrate-co-hydroxyhexanoate) (PHBH) biaxially oriented films were prepared by combination of the roll and biaxial drawing processes. Compression molded films, which consisted of large spherulite aggregation, were roll drawn up to ×1.4 and further biaxially drawn up to 3.0×3.0. The tensile modulus and the break elongation decreased while the tensile strength increased as the...
Bacterial poly[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyhexanoate] (PHBH) highly oriented films were prepared by the combination of roll and uniaxial drawing processes. The change in the higher-order structure of PHBH films was investigated by wide-angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). Extended films, which show superior mechanical properties and high ductility, have...
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