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The hot corrosion behaviour of the γ‐Y2Si2O7 ceramic exposed to NaVO3 or V2O5 molten salt was studied at 1000–1300°C. YVO4 was identified as the corrosion product due to the chemical interaction of the two corrosive agents with the γ‐Y2Si2O7 ceramic. Although YVO4 produced in the two corrosion reactions had the same crystallographic structure, they had different morphologies. YVO4 produced by the...