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Unoccupied electronic states of thin films of 3d-metal phthalocyanines (MPc: M=Mn, Fe, Co, Ni, Cu and Zn) and metal-free phthalocyanine (H 2 Pc) were investigated by inverse photoemission spectroscopy. The experimental results were analyzed with emphasis on the contribution of the 3d-metal orbitals to the lower unoccupied electronic states of MPc. The difference spectra between the sample...
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