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In this work, carbon nanodots (CDs) were prepared via a green and convenient microwave assisted pyrolysis of ionic liquids (ILs) and ethylenediamine. It was found that the synthesized IL-based CDs (ILCDs) exhibited a superior selective sensitivity for Cr(VI). Photoluminescence (PL) properties of the ILCDs were applied to determine the concentration of Cr(VI), which showed a wide linear range and a...
A new diffusive gradients in thin films (DGT) device, using Pb(II) ion-imprinted silica (IIS) as the binding agents and commercial cellulose acetate dialysis (CAD) membrane as the diffusion layer (CAD/IIS-DGT), has been developed and evaluated for sampling and measurement of free Pb(II) species. The CAD/IIS-DGT devices were successfully applied to the measurement of free Pb(II) species in synthetic...
A Hg2+-mediated fluorescence turn-on sensor for cysteine (Cys) detection was developed using the nucleic acid minor groove binding dye DAPI. In this work, two fully complementary DNA sequences, a T-rich single-stranded molecule (ssDNA) and an A-rich single-stranded molecule, were employed to constitute consecutive “AT/TA” base pairs, which could strongly enhance the fluorescence of DAPI. In the absence...
A selective and sensitive fluorescence biosensor for Ag + ions and cysteine (Cys) was developed based on the chelation actions between Ag + ions and guanine bases of G-rich fluorogenic oligonucleotide (FAM-ssDNA) and the different electrostatic affinity between FAM-ssDNA and graphene oxide (GO). FAM-ssDNA adsorbed onto the surface of GO through π–π stacking interaction between the...
Titanium dioxide nanoparticles (nano-TiO 2 ) were employed for the sorption of Te(IV) ions from aqueous solution. A detailed study of the process was performed by varying the sorption time, pH, and temperature. The sorption was found to be fast, equilibrium was reached within 8min. When the concentration of Te(IV) was below 40mgL −1 , at least 97% of tellurium was adsorbed by nano-TiO...
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