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New disilver(I) methanedisulfonates complexes {CH 2 (SO 3 ) 2 Ag 2 ·[P(OMe) 3 ] n } (n=2, 2a; n=4, 2b; n=6, 2c) were prepared by reacting [CH 2 (SO 3 ) 2 Ag 2 ], which could be synthesized from methanedisulfonic acid and Ag 2 CO 3 in water, with trimethylphosphite in dichloromethane. The molecular structure...
The preparation of [(MeO) 3 P n ·AgNC 4 H 4 O 2 ] (n=1, 2a; n=2, 2b) is described. The molecular structure of 2a was determined by using X-ray single crystal analysis. Complex 2b was tested as Metal Organic Chemical Vapor Deposition (MOCVD) precursor in the deposition of silver for the first time. The thin films obtained were characterized using scanning electron...
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