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Silicomolybdic acid is supported on the sulfonic acid‐modified MIL‐101‐Cr by diffusion method, which increases the metal active sites on the surface of the material while maintains the structural integrity of MIL‐101. The CO yield of composite SiMo12O40@SO3H‐MIL‐101‐Cr in CO2 photoreduction is as high as 82.95 μmol/(g ⋅ h), and the CO selectivity is 93.2 %. The improvement in the catalytic performance...
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