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A novel supramolecular polymer metallogel (QP5‐AlG) has been constructed by cross‐linking of bis‐8‐hydroxyquinoline functionalized pillar[5]arene with Al3+. The metallogel QP5‐AlG shows light blue aggregation induced emission (AIE) in DMSO/H2O binary solution. Interestingly, the QP5‐AlG shown multiple external stimuli‐responsive behaviors such as temperature, guest compounds, acid, base and so on...
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