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Two hydrophobic hole transporting materials (HTMs) carrying multiple thiophene cores of 5,7-bis(3-hexylthiophen-2-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxine (for SP-01) or 4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophene (for SP-02) and long alkyl substituents have been prepared through facile routes with high yields, together with the hole-transporting molecule 2,5-bis(4,4′-bis(methoxyphenyl)aminophen-4′′-yl)-3,4-ethylene...
Four novel thiocyanate-free cyclometallted Ru(II) complexes, D-bisCF3, D-CF3, D-OMe, and D-DPA, with two 4,4′-dicarboxylic acid-2,2′-bipyridine together with a functionalized phenylpyridine ancillary ligand, have been designed and synthesized. The effect of different substituents (R=bisCF3, CF3, OMe, and DPA) on the ancillary C^N ligand on the photophysical properties and photovoltaic performance...
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