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A new tetracopper(II) complex bridged both by oxamido and carboxylato groups, namely [Cu4(dmaepox)2(bpy)2](NO3)2·2H2O, where H3dmaepox and bpy represent N‐benzoato‐N′‐ (3‐methylaminopropyl)oxamide and 2,2′‐bipyridine, was synthesized, and its structure reveals the presence of a centrosymmetric cyclic tetracopper(II) cation assembled by a pair of cis‐dmaepox3–‐ bridged dicopper(II) units through the...
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