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Herein, the electronic structure and bonding character of the stable cyclo[18]carbon (C18) precursor, C18Br6, are thoroughly characterized by molecular orbital (MO), density of states (DOS), bond order (BO), and interaction region indicator (IRI) analyses. The delocalization characters of out‐of‐plane and in‐plane π‐electrons (labeled as πout‐ and πin‐electrons, respectively) in bonding regions were...
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