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Thiole sind allgegenwärtig in lebenden Systemen, und ihre starke Bindung an Goldoberflächen hält andere funktionelle Gruppen fast vollständig von diesen fern. In ihrer Zuschrift auf S. 12727 berichten J. Santamaría, A. Unciti‐Broceta et al. über Gold‐Heterogenkatalysatoren für die bioorthogonale Aktivierung zugelassener Tumortherapeutika (durch O/N‐Depropargylierung) in Krebszellkulturen und die erste...
Recent advances in bioorthogonal catalysis are increasing the capacity of researchers to manipulate the fate of molecules in complex biological systems. A bioorthogonal uncaging strategy is presented, which is triggered by heterogeneous gold catalysis and facilitates the activation of a structurally diverse range of therapeutics in cancer cell culture. Furthermore, this solid‐supported catalytic system...
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