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P-type Ba8Ga16CdxGe30-x (x=0.95, 1.00, 1.05, 1.10) type-I clathrates with different Cd contents were synthesized by combining melt method with spark plasma sintering (SPS). The effects of Cd content on electrical transport properties have been investigated. The results show that all samples exhibit p-type conduction. The Seebeck coefficient alpha and room temperature carrier mobility muH decrease...
AgPb18SbTe20 samples were prepared by cooling from melts at three different rates as quenching, furnace cooling and controlled slow cooling rate of 10degC /h, and the correlation between cooling rates and samples microstructure and thermoelectric properties were discussed. Experimental results show that cooling rates influence significantly the microstructure and thermoelectric properties of the samples...
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