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The reaction of HN3 with the strong Lewis acid B(C6F5)3 led to the formation of a very labile HN3⋅B(C6F5)3 adduct, which decomposed to an aminoborane, H(C6F5)NB(C6F5)2, above −20 °C with release of molecular nitrogen and simultaneous migration of a C6F5 group from boron to the nitrogen atom. The intermediary formation of azide–borane adducts with B(C6F5)3 was also demonstrated for a series of organic...
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