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Der α‐Effekt ist ein “Reaktivitäts‐Booster”, der dem weniger basischen Peroxid (HOO−) den Vorteil gegenüber Hydroxid (HO−) im Grand Prix der SN2‐Reaktivität verschafft! In ihrem Forschungsartikel auf S. 21008 stellen Trevor A. Hamlin et al. zwei Kriterien auf, die α‐Nucleophile erfüllen müssen, um einen α‐Effekt zu zeigen: (i) ein kleiner HOMO‐Lappen am nukleophilen Zentrum, um die destabilisierende...
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