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Development of near-infrared-emissive aza-boron dipyrromethene (aza-BODIPY) derivatives having furanyl groups is reported. From the optical measurements, it was clearly indicated that the emission bands were presented in the longer wavelength region than those of the conventional aza-BODIPYs. The emission bands with the peaks at 730nm and 758nm were observed from the bis- and tetra-substituted furanyl...
This manuscript presents the strategy for obtaining solid-emissive properties from the BODIPY dyes. It is demonstrated that the emission properties can be preserved from the aggregation-caused quenching (ACQ) by introducing the phenyl groups into their boron center. We established the synthetic procedures for the introduction of single or dual phenyl groups into the boron center in BODIPYs. The synthesized...
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