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Fluorinated completely condensed polyhedral oligomeric silsesquioxanes (F‐CC‐POSSs) are widely utilized as surface modifiers for polymeric materials because of their polyhedral and fluorine‐rich structures, which generate polymers with lower surface energies under molecular‐level control. In contrast, their derivatives, fluorinated incompletely condensed or open‐cage POSSs (F‐IC‐POSSs), have similarly...
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