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Metall/Lewis‐Säure‐Kooperation ermöglicht einen anionischen Pfad für die Palladiumkatalyse, wie H. Kameo, D. Bourissou et al. in ihrer Zuschrift auf S. 18959 berichten. Elektronenreiches Pd0, erzeugt durch Hydridinsertion in eine Pd→B‐Bindung, aktiviert Chlorarene und liefert die Dehalogenierungsprodukte über einen B‐zu‐Pd‐Hydridtransfer und reduktive Eliminierung. Diese neuartige Palladium‐Boran‐Kooperation...
Metal–Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium–borane cooperation involving anionic Pd0 species. The air‐stable DPB palladium complex 1 (DPB=diphosphine‐borane) was prepared and reacted with KH to give the Pd0 borohydride 2, the first monomeric anionic Pd0 species to be structurally characterized. The boron moiety acts as an acceptor...
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