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Three synthetic samples of six-line ferrihydrite (Fh5.4, Fh4.1, and Fh3.0), with average particle sizes of 5.4, 4.1, and 3.0nm (respectively), have been studied by low-temperature magnetic techniques, Mössbauer spectroscopy, transmission electron microscopy, and X-ray absorption spectroscopy. Magnetic data indicate that these nanoparticles are not only antiferromagnetic, but that they also possess...
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