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Alkylated meso‐macroporous Cr‐MIL‐101 hollow tubes (ACHT) are synthesized through the coordination of Cr3+ with alkylated bridged ligands. The alkylated ligands work as both bridging ligands and structure‐directing agents, which presents a new strategy for synthesizing meso‐macroporous metal–organic frameworks (MOFs). This is the first example of 1D meso‐macroporous MOF hollow tubes with large pore...
A hierarchical porous polymer (HPP), which was prepared by the imine condensation between pararosaniline base and 1,4-phthalaldehyde, has been used as the supporting material for novel shape-stability phase change materials (ssPCMs). With high porosity (91.9%), the hierarchical pores in the HPP supply sufficient space to adsorb 1-octadecanol, which is restricted in pores by the weak interactions such...
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