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Controlling the nucleation and growth of interfacial Al4C3 carbide to optimize interfacial microstructure is well accepted as a critical factor to improve thermal properties of Al/diamond composites. In this study, the nucleation and growth mechanisms of Al4C3 carbide have been studied. The inhomogeneous nucleation of Al4C3 is revealed on both diamond (100) and (111) surfaces ((100)D and (111)D surfaces)...
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