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Slip sliding away: Foldamers (see picture, red) can function as modular stoppers to regulate the slippage and de‐slippage of pseudorotaxanes and the switching kinetics and metastability of bistable rotaxanes. By simply changing the solvent or the length of the hydrogen‐bonded foldamer, the lifetime of the metastable co‐conformation state can be increased dramatically, from several minutes to as long...
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