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In this work, we have carried out ivestigations on photo-electrochemical energy conversion and storage on WO3/TiO2 hybrid materials. The band gap excitation of the hybrid WO3/TiO2 having an amorphous WO3 phase led to an effective photo-charging to form a tungsten bronze structure by the intercalation of protons while a reversible discharging through de-intercalation could also be observed.
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