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A biomimetic oxidation catalyst, metalloporphyrinic metal–organic framework, was successfully constructed by manganese tetrakis (4-carboxyphenyl) porphyrin as a bridging ligand and Fe ions with a stable 3D framework. The X-ray diffraction (XRD) spectra and X-ray photoelectron spectroscopy (XPS) details demonstrated its structure formed by channels and cavities and a catalysis-promoted electronic environment,...
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