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The pincer ligand H3L3N, bis(2‐amino‐3,5‐di‐tert‐butylphenyl)amine}, was chelated to NiII, PdII, and PtII. Square‐planar complexes of stoichiometry 2:1 (ligand/metal) formed, wherein the ligand coordinates in a bidentate fashion. By X‐ray diffraction we established that each ligand molecule coordinates in its diiminosemiquinone radical form in the neutral NiII, PdII, and PtII complexes (1, 2, and...
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