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A new Mitsubishi‐type of star‐shaped homoleptic derivative of indium(III), In4(mdea)6 (2, mdeaH2 = N‐methyldiethanolamine), was synthesized by the chloro–aminoalkoxo exchange reaction of a heteroleptic complex In6Cl6(mdea)6 (1) and used as a facile single source molecular precursor for the sol–gel preparation of high surface area indium oxide. Successful deposition of gold nanoparticles (1 wt.‐%)...
The coordination chemistry of copper, gallium and indium halides with the simplest possible selenoether i.e. Me 2 Se was investigated with the aim to use the resulting complexes as precursors for selenium-containing chalcopyrite semiconducting materials. An optimized general procedure for the high yield synthesis is described and the influence of a halide ion on the structure and solubility...
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