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The combination of single‐ion magnets (SIMs) and metal–organic frameworks (MOFs) is expected to produce new quantum materials. The principal issue to be solved in this regard is the development of new strategies for the synthesis of SIM‐MOFs. This work demonstrates a new simple strategy for the synthesis of SIM‐MOFs where a diamagnetic MOF is used as the framework into which the SIM sites are doped...
Molybdenum oxycarbide clusters are novel nanomaterials that exhibit attractive catalytic activity; however, the methods for their production are currently very restrictive. This work represents a new strategy for the creation of near‐subnanometer size molybdenum oxycarbide clusters on multilayer graphene. To adsorb Mo‐based polyoxometalates of the type [PMo12O40]3− as a precursor for Mo oxycarbide...
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