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The synthesis of tribenzotriquinacenes (TBTQs) that bear three phenylethynyl groups at the peripheral positions of the bowl‐shaped molecular scaffold has been achieved by use of different strategies. Although the C1‐ and C3‐symmetrical triformyl, triethynyl and triiodo derivatives were inseparable by chromatography, the corresponding C1‐ and C3‐symmetrical tris(phenylethynyl)tribenzotriquinacenes...
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