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We have investigated the HO2 adsorption and acid dissociation process on the surface of (H2O)20 and (H2O)21 clusters by using quantum‐chemistry calculations. Our results show that the radical forms a stable hydrogen‐bond complex on the cluster. The HO2 acid dissociation is more favorable in the case of the (H2O)21 cluster, for which the inner water molecule plays a crucial role. In fact, acid dissociation...
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