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Guilty as charged: Germanium(II) and tin(II) monocations which are stabilized by an extremely bulky amido ligand and a very weakly coordinating anion are reported (see picture; E=Ge, Sn; PF=[Al{OC(CF3)3}4]−). The metal centers exhibit weak intramolecular η2‐arene interactions, and preliminary reactivity studies highlight the electrophilicity of the cations.
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