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Edge Reconstruction
An unprecedented U‐edge reconstruction with the lowest energy is revealed to occur easily in the bilayer phosphorene. Such U‐edge reconstruction exhibits unexpectedly ultrafast electronic and thermal transport, nearly without edgeless scattering. More information can be found in article number 2105130 by Junfeng Gao, Gang Zhang, and co‐workers.
Edge termination plays a vital role in determining the properties of 2D materials. By performing compelling ab initio simulations, a lowest‐energy U‐edge [ZZ(U)] reconstruction is revealed in the bilayer phosphorene. Such reconstruction reduces 60% edge energy compared with the pristine one and occurs almost without an energy barrier, implying it should be the dominating edge in reality. The electronic...
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