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An ultrathin self‐assembly monolayer of rubrene on Au(111) has been fabricated and studied by scanning tunneling microscopy. The apparent thickness of such monolayer is 0.08 nm and close to the radius of a carbon atom. Moreover, the rubrene molecules within the second layer prefer adsorbing on to the positions corresponding to the herringbone structure underneath the Au(111)–() while the Au surface...
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