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We previously reported a cyclic Zn(II) porphyrin trimer in which three Zn porphyrins are alternately bridged by three 2,2′‐bipyridine (bpy) moieties, enabling the encapsulation of metal complexes within the nanopore formed by the Zn porphyrins. In this study, we introduced a [Re(CO)3Br] fragment into one of the bpy moieties of the cyclic trimer to form the catalytic Re(4,4’‐R2‐bpy)(CO)3Br center (R=methyl...