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H2‐Bildung: Die Reaktion des sauren Wolfram(II)‐hydrids 2 mit dem Nickel(II)‐Pinzettenkomplex 1 in THF oder Toluol führte nach Bildung einer H‐H‐Brücke zur Ni‐W‐Spezies 3 (siehe Bild). Das erste Beispiel für eine H‐H‐Brücke zwischen zwei Metallhydriden mit entgegengesetzter Polarität wurde anhand von NMR‐ und IR‐Spektroskopie, Röntgenstrukturanalyse und DFT‐Berechnungen untersucht.
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